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Results show that the more densely crosslinked the network, the more heterogeneous is its structure.
Although PEG-D4 cured rapidly (under 30 s), catechol continues to polymerize over several hours to form a more densely crosslinked network over time.
However, in this case, the porogen evaporation might be supplemented by post-curing of dangled CER chains finally resulting in modified porosity of the more densely crosslinked resulting CER material.
The surface region of SAP spheres was additionally crosslinked with ethylene glycol diglycidyl ether (EGDE) to improve the mechanical properties, producing a core-shell structure characterized by lightly crosslinked core and more densely crosslinked shell.
A lithographic scheme utilizing photocrosslinking of ion-exchanged PS- b-P2VP film was developed using the strength of UV exposure energy control the degree of blue shift in color of the photonic gels (a more densely crosslinked gel leads to less swelling).
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The stress on cure ranged from less than 1% of the total stress on cure and cool-down in a lightly crosslinked epoxy to more than 30% of the total stress in densely crosslinked epoxies and acrylates.
Densely crosslinked networks with gel contents up to 98% could be obtained in this manner.
Herein, we investigated the photogenerated strain under uniaxial loads in densely crosslinked azobenzene-incorporated liquid crystalline polymer (azo-LCP) actuators.
In densely crosslinked glassy thermosets, at yield, bond length and bond angle deformations, transition to cooperative deformation of multiple effective network chains via bond torsions.
Unlike densely crosslinked protein matrices, which are commonly intended for industrial bulk applications, site specifically linked fusion proteins are usually produced on a comparably small scale.
Both have a densely populated place called Manhattan (one admittedly more densely populated than the other).
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