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At low dilution (more concentrated solutions), formation of stars with hundreds of arms and then gelation are observed.
The presence of pseudotetrahedral complex NiCl3DMF− and the existence of coordinative disproportionation equilibrium have been established in the more concentrated solutions of NiCl2.
Since the chemical crosslink density was the same for all the networks, those formed from the more concentrated solutions had a higher number of physical entanglements.
It has been demonstrated that after measuring the PPy films in different NaCl solutions, both the rate of ionic exchange and the diffusion processes through the membrane are faster for more concentrated solutions.
In diluted HCl (< 1 N), the rate of growth is small but the resultant film has better electrochemical insulating properties than that rapidly grown in the more concentrated solutions.
In more concentrated solutions and at higher q, however, interpretation of the scattering behaviour for polymers associating via an open association mechanism (OAM) is more difficult, particularly if, as in this investigation, the single chains and aggregates have varying densities and fractal parameters.
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They then added a dilute concentration of potassium chloride to one protocell and a more concentrated solution to the other.
Calibration difficulties can be encountered if a more concentrated solution is employed, because Cs+ can, quite surprisingly, achieve a superequilibrium concentration early in the flame.
Due to osmosis, additional pressure is required to force water out of a more concentrated solution.
Coordinative disproportionation producing the CoCl3DMSOt- complex anion is shown to predominate in the more concentrated solution of CoCl2 in DMSO.
The concentrated inulin solution was then submitted to a lowering of the temperature followed by centrifugation for phase separation, to obtain a more concentrated solution.
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