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They produce much more complex spectra, but basic relationships, analogous to those for a diatomic molecule, exist between their moments and the observed absorption lines.
Although the Ratip program focus on properties with just one electron within the continuum, recent emphasis was placed also on second-order processes as well as on the combination of different types of transition amplitudes in order to explore more complex spectra.
All synthetic melanins displayed strong electron paramagnetic resonance (2.14·1018, 7.09·1018, and 9.05·1017 spins/g, respectively), with sulfur-containing melanins demonstrating more complex spectra and higher numbers of stable free radicals.
MELex5, MEL1, and MEL2 gave single-line EPR spectra, while MEL3b and MEL4 gave more complex spectra which both had an additional peak, presumably due to hyperfine splitting of a radical centered at a 14N nucleus.
Silicone and polystyrene have slightly more complex spectra which are also weaker.
In this manuscript, we use the spectra resulting from ESI rather than the more complex spectra resulting from MALDI, which will be the focus in later manuscripts in the series.
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Still down the road is the complex world of rehabilitation, either home-based or institutional, and the even more complex spectrum of available nursing options for the slightly impaired, the seriously impaired and those near death.
The frequency analysis shows that the fast ramp loading generates a more complex spectrum than for the static load with the appearance of new resonance peaks.
Developing the algorithm further so that it can become more nuanced – in terms of being able to pick up on a broader and more complex spectrum of emotions than just the core five, such as say boredom or disgust — would certainly be a lot more challenging, says Dobson, noting that the differences between vocal signifiers can be subtle.
Red areas gave rise to the Raman spectrum of vermilion (HgS, Fig. 4d), whereas the orange areas yielded a more complex spectrum, which consists of a combination of massicot (PbO) and red lead (Pb3O4) (Fig. 4c).
The generally beneficial effects of hypercapnic acidosis in the setting of experimental non-septic inflammatory injury contrast with a more complex spectrum of effects in the setting of live bacterial infection.
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