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Exact(33)
Experimental measurements of the reduced viscosity, ηred, of a 3% (w/w) dispersion, as a function of temperature and electrolyte concentration, provided further evidence of a temperature-induced conformational change with respect to the poly NEAM) chains, resulting in a more compact conformation.
The polymer chains present a more compact conformation at higher temperatures, losing contact with the water molecules.
In dilute solution, the polymers form intermolecular aggregates with a more compact conformation than that of precursors.
SANS data show both a more compact conformation for a copolymer guest molecule than for a linear guest and also a smaller molecular expansion with increasing molecular weight when both guest and host are copolymers.
This suggests the presence of a more compact conformation but without any predominant secondary structure elements.
These specific rearrangements lead to a more compact conformation resulting in a 5% decrease in the volume of the LBP compared to 1α,25(OH)2D3.
Similar(26)
The diffusion of such bioactive molecules in solution should be less easy from humic matrices with larger and more compact conformations [37,38,69].
Finally, an unexpected finding of this study is the stabilization in water of the more compact conformations of the polymer chains with a fixed dipole moment.
By folding and assuming more compact conformations with smaller interfacial area, proteins can lower this free energy penalty.
Subunits embedded in vitreous ice appeared as thin straight rods but the use of a molybdate staining solution and/or glutaraldehyde favored more compact conformations and aggregation into meshworks.
Such interactions are ubiquitous in highly volume-occupied physiological fluid media, and result in significant size- and shape-dependent repulsive contributions to the chemical potential of each macromolecular species that tend to stabilize more compact conformations relative to less-compact conformations [12], [13].
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