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In-situ Raman spectroscopy indicated that the electrode surface is covered by Mn3O4, Mn2O3, and MnO2 as the potential is shifted towards more anodic values.
As shown by DEMS, the surface modification shifts the onset potential for oxygen evolution reaction on the Cu PVC composite electrode towards more anodic values.
The shift of the anodic peak (I) potentials to more anodic values compared to that for pure cobalt is probably due to the presence of phosphorus in the cobalt deposit.
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In a short immersion period, up to two hours, the impedance measurements showed a marked decrease of the charge transfer resistance, thus indicating the acceleration of the corrosion rate, whereas the electrode potential shifted towards a more anodic value.
Lower current densities and more anodic E ocp values were recorded for AISI 316L.
The results show that chloride threshold is independent of the potential for values more anodic than −200±50 mV (SCE) being this region the typical potentials exhibited by passive reinforcements in atmospheric conditions.
Low capacitance values obtained at potentials more anodic than 0·8 V vs nhe give a linear1/C2vs E (Mott Schottky) plot.
If reduction reactions are studied, the electrode is made more cathodic (negative); if oxidations are studied, the electrode is made more anodic (positive).
But as the concentration reached to 200 ppm, electrode potential shifted to more anodic side.
When 100% calcium acetate was used, the corrosion current moved to anodic values and no corrosion was observed.
Initially, cyclic voltammetry was used with the Mg alloy being cycled from OCP to more anodic potentials.
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