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The analyses were performed in positive selected ion monitoring mode for m/z = 278 (corresponding to the protonated molecule [MH+] of [19F]CFT), and the SAs are decay corrected to the EOS.
The ESI-MS/MS was operated in the multiple reaction monitoring mode for monitoring transition pair of the individual protonated parent ions and their common daughter ion m/z 264.
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Spectrometric detection was performed using a triple quadrupole mass spectrometer in selected reaction monitoring mode, monitoring for the individual m/ z transitions for each of the 10 PFCs and the C-PFOA surrogate.
Ions were generated by ESI source and analyzed by multiple reaction monitoring mode (basis for quantification) in the Agilent 6410 QqQ analyzer.
Detection was performed using a triple quadrupole mass spectrometer in selected reaction monitoring mode, monitoring for the M/Z transitions of 10 individual perfluorocarbon compounds and an internal C-PFC standard corresponding to each target compound analyzed.
Detection relied on a triple quadrupole mass spectrometer in preselected reaction monitoring mode, monitoring for the M/Z transitions of ten PFAA species with an internal C PFAA standard corresponding to the target compound.
The samples were analyzed for 64 organic compounds, including pesticides, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls (PCBs), using GC/MS in multiple ion monitoring mode; and for nine metals using conventional microwave-assisted acid digestion combined with ICP/MS.
The precursor-to-product ion transitions in multiple reaction monitoring mode m/z 353.1-193.1 (for 8-iso PGF2α) and m/z 357.1-197.1 (for internal standard: 8-iso PGF2α-d4) were used for quantitation.
For quantification of GCs, the ESI-MS/MS was operated in the multiple reaction monitoring (MRM) mode for monitoring transition pair of the individual protonated precursor ions and their common product ion m/z 264.
Solvent delay was set to 4 min. Selected ion monitoring mode was used for the qualitative and quantitative determination of fatty hydrocarbons.
An ultra performance liquid chromatography-triple quadrupole-linear ion trap mass spectrometry method in multiple-reaction monitoring mode was developed for the rapid determination of 12 bioactive compounds in the leaf and stem of Andrographis paniculata (A. paniculata).
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