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MS detection was realized in multiple reaction monitoring mode, and the carbonyl compound concentration (expressed in μg/cigarette) was calculated using an external calibration curve.
The analytes were detected in ESI+ with multiple reaction monitoring mode and fragmentation conditions were optimized to obtain the highest sensitivity.
The method was based on selective liquid/solid extraction, combined with liquid chromatography electrospray ionization tandem mass spectrometry in the multiple reaction monitoring mode and negative ionization.
Analysis was carried out using the dynamic multiple reaction monitoring mode and fast polarity switching.
Compounds were analyzed in multiple reaction monitoring mode and quantified by using surrogate corrected calibration curves.
Acquisition was performed in the selected reaction monitoring mode and the chromatographic run was divided into two individual periods with a settling time of 50 ms.
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Engineering of optical captors allows facile and reliable signaling in continuous monitoring modes, and enables simple and high-speed removal of toxic chromium (VI) ions.
The other laptop on the train, on the other hand, acted as a sniffer running in the monitor mode and using Wireshark[20] to sniff and log the information of the transmission packets.
PCDD/Fs and PCBs were analyzed with HRGC/HRMS using a selected ion monitoring mode (SIM) and resolution of 10 000.
One has to bear in mind, however, that when combining both bioassay monitoring (mode 1) and analyte/ligand identification (mode 2), the analyte/ligand identification part is hampered by the post-column bioassay dilution and buffer conditions that are less favorable for typically used positive ESI ionization (low organic modifier concentration at a bioassay-compatible pH of ~6 to 7.5).
The FAEEs were detected with electron ionization (70 eV) in scan mode (50 to 650 m/z) and selected ion monitoring mode at m/z 88 and 55 (for quantitative analysis).
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