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Dulić, D. et al. One-way optoelectronic switching of photochromic molecules on gold.
Initial essays were able to suggest the orientation of molecules on gold nanoparticles surface.
We find that the photoemission and inverse photoemission final states are well screened for these dipolar molecules on gold.
Two redox peaks were recognized in the cyclic voltammograms, indicating that 11-FUT molecules on gold substrates have two different states.
Hyperbranched thin film (HTF) with amino and imino groups, which can accommodate PtCl62−, was synthesized with small organic molecules on gold substrate based on SN2 displacement reaction.
The absence of infrared absorption bands from these adsorbates agrees with a flat, almost parallel adsorption of TMTU molecules on gold that has been already reported.
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We first incubated a solution of CH3-terminated thiol molecules on gold-coated glass for 24 h. Figure 1a shows an AFM topography image of this thiol SAM in air.
The prominent role of weak H-bonds in the 2D arrangement of this molecule on gold is supported by ab initio calculations of intermolecular interaction energies (E = 3.1 kcal/mol) and H-bond lengths (L = 2.55 Å).
The tip is placed in contact with a self-assembled monolayer of p-nitrothiophenol molecules adsorbed on gold nanoplates.
Furthermore, we used dipolar-filtered 1H solid-state nuclear magnetic resonance to characterize the mobility of the molecules confined on gold.
Indeed, the increase of density of PEG5000 molecules grafted on gold NP was accompanied by the systematic increase of NP hydrodynamic diameter [30].
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