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The crystal structure of 1 reveals that the ligand molecules bridge the tetrahedral ZnII centers (ZnN2Cl2) in the unprecedented transoid conformation, forming a one-dimensional zigzag coordination chain.
The bidendate bipy molecules bridge the CuII centers to form a 2-D bilayer framework with an 82 · 10 topology, and the monodendate bipy ligands, locating up and down each 2-D architecture, are involved in significant aromatic stacking interactions with the adjacent 2-D motifs, resulting in a 3-D porous network with large square channels for including the guest solvents and anions.
Their method has been evaluated with considerable improvement by using 12 structurally diverse complexes, where several water molecules bridge the ligand and the target.
In the crystal structure of cPAH and an oxidized form of the cofactor, 7,8-dihydrobiopteirn (BH2), three water molecules bridge the interaction between D139 and the cofactor; one of the waters also occupies a coordination site on iron.
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In the absence of molecules bridging the tip substrate gap an exponential current decay is recorded.
In the case of short time observations, the results of the model for the probability of observing a given number of molecules bridging the gap are compared with the experimental results from the literature, showing a good predicting power.
A recent analysis of high-resolution crystal structures of ligand-protein complexes revealed that 85% of the complexes had one or more water molecules bridging the interaction between ligand and protein.
They function as cell adhesion molecules, bridging the synaptic cleft.
However, the NBDs associate as head-to-tail dimers [ 41], with ATP molecules bridging the interface to interact with Walker A and B motifs in one subunit and with an ABC-specific signature motif in the partner subunit.
In many cases, we observe the non-intercalated end of the polymer intercalating into another interlayer spacing within the tactoid; we illustrate this in Figure 8, where polymer molecules bridge between the first and the third interlayer spacing.
(a) Schematic of a S- CH2 4-Fc- CH2 4-S S- CH2 4-Fc- CH2 4-S S- CH2 4-Fc- CH2 4-S S- CH2 4-Fc- CH2 4-S S- CH2 4-Fc- CH2 4-S
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