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MTANs also stabilize a specific water molecule adjacent to C1′ as the incipient nucleophilic group.
Interestingly, the crystal structure of HemN contains a second SAM molecule adjacent to the first SAM that binds to the [4Fe-4S] cluster.
Via analysis of the system after MD equilibration, the only two possible receptors of the proton were Glu102 and the water molecule adjacent to this residue.
The crystallographic and mutational study by Henderson and Remington supports the conclusion that the water molecule adjacent to Ala165 has a less significant contribution than His199 [ 20].
The observation of the hydrogen bond between the CBZ molecule adjacent to the heme and the S119 residue provides a clue to the effects of the S119A substitution.
This result is essentially consistent with previous studies of amFP486 which have suggested complementary roles for His199 and the water molecule adjacent to Ala165 in achieving the blue-shift [ 20, 23].
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Molecules adjacent to the metallic nanostructures exhibit significantly enhanced Raman signals [8 11].
Water molecules adjacent to the surface were found to only weakly interact with the surface and as a result were readily able to exchange with the bulk water.
We inferred that the electron transfer reaction is kinetically limited by the electron communication between MP-11 molecules adjacent to the electrode and the electrode.
Electric fields and potentials of an equilibrated assembly of ions and water molecules adjacent to a charged metal surface are calculated as a function of perpendicular distance z from the surface from data derived from molecular dynamics trajectories.
Endogenous as well as radiation-induced DSBs provoke a DNA damage response characterized by the activation and recruitment of ATM (Ataxia Telangiectasia mutated) leading to the phosphorylation of Ser-139 of histone H2AX molecules adjacent to break sites.
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