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Chemical substitution in the molecular wire also has an effect on the electronic structure; however, energy level shifts are larger for conformational changes than for chemical substitution.
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These results not only demonstrate a new strategy to design new families of highly conductive and tunable nanoscale molecular wires, but it also brings a new nanoscale electrical platform to help understanding some fundamental mechanistic aspects of molecular electrocatalysis.
Thus, aromaticity may be also employed to enhance the electron transport in a molecular wire.
Intermolecular exciton migration is observed in unmodified molecular wire OPE1; while only intramolecular exciton migration is allowed in the side-chain modified molecular wire OPE2.
This wire also crosses the medial face wire at nearly 90°.
This research sheds a light on the molecular design for the molecule serving as the molecular wire.
Efficient ET could be observed even for larger distances between isoalloxazine and "molecular wires", when the flavoenzyme glucose oxidase was reconstituted on gold electrodes, but using molecules other than DNA (e.g. single-walled carbon nanotubes) as the molecular wire.
Steel wire also should be avoided if possible.
Molecular electronics will also require reliable molecular wires to carry signals from one molecular circuit element to another.
Researchers will probably also need to figure out ways to push higher electrical currents through the molecular wires to make magnetic sensors that can compete with current technology.
A theory related to electronic conduction through individual molecular wires, attached at one end to a substrate and probed at the other end by an STM tip, has also been presented.
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