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The peak of 1 at around 15 min detected by RI trace shifted to the low molecular weight side after the polymer reaction (Fig. 2b).
The molecular weight of 2 was calculated from only the low molecular side peak (Fig. 2b, 14.2 min) because the high molecular weight side peak could not be used as it was too high (Fig. 2b, 8.1 min).
A library of 13 polylysine-graft-imidazoleacetic acid conjugates was synthesized to examine the collective effects of polymer molecular weight, side chain substitution, and DNA:polymer ratio on cytotoxicity, transfection efficiency, and polycation DNA interaction.
This problem is most often encountered on the low molecular weight side when light scattering or viscometer signals have a lower sensitivity than concentration-sensitive detectors such as refractive-index detectors.
We noticed that the UV trace of Fam20A/C complex was slightly asymmetric with a lag on the lower molecular weight side, indicating heterogeneity and partial dissociation of the complex.
In this work we employ RAFT/MADIX polymerization methodology to access a library of well-defined polymers to investigate how their structural features (molecular weight, side chains) influence nucleation as a first step to understanding and predicting new synthetic materials capable of reproducing extremophile function.
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The permeability to oxygen of silicone polymer networks with controlled high-molecular-weight side chains was measured using electrochemical techniques.
These studies show the effect of structure, molecular weight, composition, side groups and thermal history on the thermal transitions of these materials.
Moreover, the investigation of working mechanism interestingly showed that lowering molecular weight and side chain length and introducing hydrophobic groups can achieve improved dispersion capacity and viscosity-reduction effectiveness.
Effects of polycarboxylate (PCE) superplasticizers with different densities of carboxylate groups, functional group contents, molecular weight, and side chain polymerization degrees on the hydration behavior of Portland cement were investigated in this study.
In this Feature Article, we focus on how the orientation of semiconducting polymer backbones are influenced by the chemical structure, e.g., backbone structure, molecular weight, and side chains, and processing conditions.
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