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High molecular weight samples of the novel biodegradable polyester poly ethylene sebacate) (PESeb) were synthesized.
The Pisa structure was found to disappear from slowly cooled low molecular weight samples.
The present study on the two different molecular weight samples showed that molecular weight does not influence the α2 formation.
The structure of end groups also affects the cloud point of PMAIPAC particularly for low molecular weight samples at low pH.
The position of the maximum and the amplitude of this maximum is analyzed for the low molecular weight samples in the dilute regime.
This technique clearly showed that the broader molecular weight samples possessed fibril nuclei that were not evident in the narrower molecular weight distribution films.
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For slowly cooled high molecular weight sample, the Pisa structure became less salient.
'Sharkskin' and 'slip-stick' effects observed in extrusion process of the high molecular weight sample disappear for blends of 50% and higher content of low molecular weight polyethylene.
As a consistent approach, we have also combined the effective dimensions with the wormlike chain model to calculate the persistence length of the higher molecular weight sample, Na50PA48.
Carboxylic acid functionality significantly increased the hydrolytic degradation rate and mass loss behavior for the 5000 g/mol material, but did not affect the hydrolytic degradation rate for the higher molecular weight sample.
This mechanism is not sufficient to form intermolecular aggregates in the case of lower molecular weight (sample 1).
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