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With low molecular weight reactants, homogeneous, single-phase materials are produced which exhibit the same thermal and mechanical properties regardless of whether reactions are sequential or simultaneous.
A model reactive system was defined for studying experimentally and by simulation the competition between reaction and diffusion of two low molecular weight reactants, 2,3-epoxypropyl-phenylether (EPPE) and dipentylamine (DPA).
With some higher molecular weight reactants, e.g., 2000 g/mol diacrylate, novel phase-separated thiol-acrylate-epoxide polymer networks are produced with properties that are highly tunable by sequential reaction order.
The low molecular weight reactants, unlike enzymes, are small enough to penetrate the wood lignocellulose fabric, and have been shown in immunolabeling studies to be present throughout the S2 layer of the brown rot-degraded cell wall [ 21].
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Metabolomics is the identification and quantification of metabolites (i.e., low-molecular-weight reactants, intermediates, or products of biochemical reactions) in a biological system (1, 3).
The reaction energy was therefore calculated using the information in Table 1 together with Equation (10): (10) Q r e a c t i o n = ∑ (m b × c r × x r × Δ H f / M w ) where c r and x r are the composition of the reactant in the biomass and the conversion rate of the reactant to the product respectively and M w the molecular weight of the reactant.
It is disclosed that some factors, such as mole ratio of the ternary reactants, molecular weight of epoxy resin, even the hydrophilic solvent content of system, play important roles in the gelling effect of esterification reaction.
The molecular weight of the residual reactant decreased with increasing bioconversion temperature whereas the opposite trend was observed for its polydispersity index.
The goal was to establish a method to prepare N-sulfo, N-acetyl heparosan of the desired N-acetyl content, number average molecular weight, and in maximum yield by controlling the reactant concentrations, reaction time and reaction temperature.
The molecular weight and end group functionality were controlled by the reactant stoichiometry.
Considering its uniform structure, molecular weight, and polydispersity, PLEG 4 was selected as the reactant for downstream reactions with PEG and HDI.
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