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Low molecular weight materials tended to fail in a brittle manner, whereas high molecular weight materials exhibited ductile failure.
Furthermore, low molecular weight materials have increased creep compliance and creep compliance rate and are more sensitive to temperature than the high molecular weight materials.
Polymers are high molecular weight materials whose performance is largely determined by its molecular architecture.
Low molecular weight materials are less influenced by the effects of physical ageing.
As a result of the expansion of beam production to very high molecular weight materials, a new way to view the relationship of beams to high technology is discussed.
Lower molecular weight silicones led to the most rapid denaturation and aggregation, and when examined in blends of silicones at a fixed viscosity of 1000 cSt, commonly used for syringe lubrication, more rapid denaturation/aggregation was noted in blends of silicones containing the largest fractions of low molecular weight materials.
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The draw stress was increased significantly with higher molecular weight material.
The MALDI-TOF MS data also indicated an abundance of low molecular weight material 250 300 Da.
The gel-content measurement showed the importance of a high molecular weight material for the gel formation.
In addition, the activation volumes are larger and the electrical conductivity is smaller for the higher molecular weight material.
In low molecular weight material it is necessary to retain a sufficiently intact network which can orient the crystallites effectively and which prevents the material from becoming friable.
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