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This behavior can be explained by the stiffness decrease according to the PEGDA molecular weight increase.
The chain extender was added via a master-batch approach in order to promote clay delamination before molecular weight increase.
Degradation of polymers is usually manifested in a reduction of molecular weight, increase of crystallinity in semicrystalline polymers, increase of material density, a subtle increase in yield strength, and a dramatic reduction in toughness.
Degradation of polymers is usually manifested in a reduction of molecular weight, increase of crystallinity in semi crystalline polymers, increase of material density, a subtle increase in yield strength, and a dramatic reduction in toughness.
The effect of ionizing radiation on polymeric materials has been found to manifest itself in two ways: (i) as a molecular weight increase (cross-linking); and (ii) as a molecular weight decrease (chain scission degradation).
In contrast to the conventional PDLCs derived from photo-initiated step-growth polymerizations, these PDLC films were formed using photo-irradiation of initially homogeneous syrup comprised of highly functional free-radical monomer and liquid crystal, resulting in rapid molecular weight increase and network formation prior to or in conjunction with phase separation.
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The number-average molecular weight increased with decreasing UV intensity.
Retention times increased as PEG molecular weight increased from 10 kDa to 40 kDa, while selectivities decreased as PEG molecular weight increased.
As PEG molecular weight increases, volume of the as-prepared microstructures increases but density decreases.
The polymer molecular weight increases with decreasing dose rate and increasing monomer concentration.
The molecular weight increases continuously with increasing EA content in the two copolymers.
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