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Some, for instance, undergo changes in molecular weight due to cross-linking or chain scission (breaking of the chemical bonds that hold a polymer chain together).
Also, microwave irradiation method gives higher molecular weight due to prevention of the chain transfer.
The resulting tannin polymer possesses higher molecular weight due to formaldehyde and the subsequent crosslinking.
At higher catalyst concentrations these properties decreased along with the PP molecular weight due to chain-scission reactions.
The same behavior was observed for a pre-irradiated PVME (γ-irradiation) with higher molecular weight due to intermolecular crosslinks.
Because molecular stability increases with increasing the molecular weight due to which molecules vibrate in the least volume of the unit cell for occupying the equilibrium state.
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Materials incorporating CF3 groups ortho to the ether bond have low molecular weights due to the instability of the CF3 group in the polymerization process.
This theoretical work evaluates the errors in average molecular weights due to instrumental broadening when a size exclusion chromatograph is fitted with ideal on-line Mn or MW sensors, and a correction method is proposed to compensate for such errors.
In addition, all polymers derived from 2,2′-linked 9,9′-spirobifluorene and naphthalene bisimide and/or benzothiadiazole showed very low molecular weights due to the low reactivity of the active species.
The molecular weights of these constructs measured on SDS-PAGE differ from the calculated molecular weights due to abnormal behavior of NF proteins on these gels [29].
Maleimide binds to free thiols on thioredoxin and upon SDS-PAGE separation and blotting with an anti-thioredoxin antibody gives a characteristic ladder pattern which is a mixture of thioredoxin with different molecular weights due to MM PEG 24 conjugation to ≥1 of the 4 free thiols of thioredoxin (Fig. 4B, lane 2).
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