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The Gmax shows remarkable molecular weight dependence.
Bermúdez, H. et al. Molecular weight dependence of polymersome membrane structure, elasticity, and stability.
The molecular weight dependence (Ma) of [t-Bu][i-Pr] is expressed by that of Rpbull;/[Rt].
Overall crystallization rates exhibit a molecular weight dependence and a discontinuity with respect to crystallization temperature for the fractions.
An earlier study of a polysiloxane SCLCP observed similar behavior, but with a smaller molecular weight dependence of τr.
Similarities and differences of linear HDPE and PPDL molecular weight dependence on their mechanical and thermal properties were also compared.
Similar(26)
No molecular-weight dependence is found for the investigated system.
These results are discussed in terms of surface migration mechanisms based on entropic driving forces and the molecular-weight dependence of the mutual diffusion coefficient of PS-b-PMMA in PS.
In order to investigate the molecular-weight dependence of the copolymer composition, copolymerisations of styrene and butyl acrylate are carried out at 50 and 90°C in the presence of mercapto ethanol.
Theories based on the worm-like touched-bead model were used to treat the molecular-weight dependence of the intrinsic viscosity and to estimate the conformational characteristics (Kuhn statistical segment length lK, Flory characteristic ratio C∞, and steric factor σ). Low values of these characteristics indicating rather high flexibility of the chain are discussed.
The differences between the true and apparent values of molecular weight, MWD and Mw/Mn depend on and are expressed in terms of the parameters of the Mark Houwink Kuhn Sakurada equation, describing the molecular-weight dependence of intrinsic viscosity, for the polymer to be analyzed and the polymer used for calibration.
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