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Good molecular weight control was obtained.
Mechanical properties of the multiblock copolymers can be tuned by the sufficient molecular weight control of PS chains.
Film samples were synthesized through a stepwise imidization procedure wherein molecular weight control was effected through stoichiometric offset.
In all cases, the final copolymers were near-monodisperse (Mw/Mn < 1.15) and good molecular weight control was achieved.
The SEC analysis of the synthesized diblock copolymers confirmed the importance of solvent on the molecular weight control.
In all cases, the final copolymers were near-monodisperse (Mw/Mn's < 1.2) and good molecular weight control was achieved.
Similar(41)
The cocatalytic effect of oxygen was remarkable and the molecular weight controlling effect of mercaptan was notable.
The RAFT polymerizations of EES and TCLES were found to proceed in controlled fashions under suitable conditions, as confirmed by the formation of narrow polydispersity products, molecular weights controlled by the monomer/chain transfer agent ratio, and linear increases in molecular weight with conversion.
Adjustment of prepolymer molecular weight afforded control over network crosslink density.
Random poly DMA-co-NAS) copoly DMA-co-NASwere synthesized with a 75/25 molar ratio, high conversion, an excellent molecular weight (MW) control from 5000 to 130 000 g mol−1, and low poly DMA-co-NASindex (Mw/Mn<1.1).
As expected for a stably chelated metal-ion species with a relatively small molecular weight, the control mixture cleared completely from group III within 3 hours.
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