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It is shown that the new transition does not originate from a molecular transition in any of the constituents.
Differential Scanning Calorimetry confirms the onset of the major molecular transition around the same temperature with an enthalpy change of ΔH ∼379 J/gm and thermo-gravimetric analysis shows a ∼7.5% mass loss in the said transition.
This is theoretically shown to be a 'micromechanical transition', and is explained by the change in relative moduli values of the components in the matrix-interphase-particle structure of the blends, and not to originate from a molecular transition in any of the constituents.
This particular process is related to the molecular weight, the chain entanglement, the molecular transition at elevated temperatures from expanded coils to collapsed globules of a portion of the polymers, and the subsequent aggregation of the collapsed globules to make weak physical junctions.
Analysis of the IR spectra for different wavenumber regions (CH, CO, and COC stretching vibration regions) showed that PHB chains underwent a molecular transition from a random coil to a helix indicating formation of a crystalline phase following a liquid−liquid phase separation during gelation.
Mechanical performance of ELPs is accompanied by an extraordinary biocompatibility, presenting an outstanding acute, smart and self-assembling nature, based on the molecular transition of the polymer chain, in the presence of water, when their temperature is raised above a certain level.
Similar(39)
Molecular Transitions Observable by Infrared Techniques, Gisbert Winnewisser and Martin Harwit, Les Spectress des Molecules Simples au Laboratoire et en Astrophysique," pp. 458-459, Liège, June 1977.
Yet, the molecular transitions between the inactive and active conformational states are poorly understood.
In 1946 principles of the use of atomic and molecular transitions for regulating the frequency of electronic oscillators were described, and in 1947 an oscillator controlled by a quantum transition of the ammonia molecule was constructed.
We have found that mechanical unraveling of fibrin ogen) is determined by the combined molecular transitions that couple stepwise unfolding of the γ chain nodules and reversible extension-contraction of the α-helical coiled-coil connectors.
The scanned frequency range is chosen in such a way to probe simultaneously the two absorption molecular transitions of CO2 and H2O.
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