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The influence of molecular side groups into ruthenium-dye molecules is discussed in terms of the cells' efficiency.
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These studies show the effect of structure, molecular weight, composition, side groups and thermal history on the thermal transitions of these materials.
PANiCNQ combines a fully conjugated nitrogen containing backbone with molecular charge transfer side groups and this combination gives rise to a stable polymer with a high density of localised spins which are expected to give rise to coupling.
Moreover, low exposure energy (4 80 mJ cm−2) and annealing temperature (<140 °C) provided sufficient cooperative molecular reorientation of both side groups with a large reorientational order (S > 0.5).
Relative energetic positions, varied also by intra-molecular interactions of functional side groups, determine the effective band gap.
Taking into account the molecular structure of the mesogenic side groups, the results seem to show that the observed relaxations are associated with reorientation of the transverse and longitudinal components of the mesogenic side groups.
Their hydrodynamic volume could be controlled in the range of 10 30 nm in diameter depending on the length of the side groups and the molecular weight of the polymers.
A series of molecular organic semiconductors constituting of two side groups R, R = silole or silole-benzene, attached symmetrically to a central dibenzothiophene-S,S-dioxide unit were theoretically designed as host materials in red phosphorescence.
All these steroids are characterized by no or small side groups on their molecular scaffold, particularly at C17 position which is always a keto group in this group.
Copolymer ethylene-dimethyl-aminoethyl methacrylate (EDAM) with 3.9% DAM side groups and ultra-high molecular weight polyethylene (UHMWPE) were blended in decalin solvent.
It has, by linear chains of repeated molecular groups (H2C HC) n with pendant carbazole side groups [(C6H4 2NH], arranged randomly around the same chain.
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