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Whether the interconversion is considered a chemical or a molecular relaxation process is largely a matter of definition.
Furthermore, when d ≤ 200 nm, an additional molecular relaxation process, not observed in bulk, was present.
This shift in the molecular relaxation process is attributed to the partial miscibility of the two polymer components in the blends as previously confirmed by the morphology via STEM.
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The molecular relaxation processes, characteristic of pure components, are preserved in these composites.
The constitutive model accounts for the rate and temperature dependence of the stress strain behavior by modeling the competition between molecular orientation processes and molecular relaxation processes.
The tensile yield behaviour of an aliphatic polyketone is studied in relation to the molecular relaxation processes present in the polymer.
To shed light into the origins of the special behavior of the hybrids, we investigated the molecular relaxation processes in the hybrids using broadband dielectric spectroscopy.
The molecular relaxation processes, characteristics of pure components, are modified in the composites due to strong intermolecular interactions between the macromolecules.
Two molecular relaxation processes (α and β relaxations) have been found below room temperature via dynamic mechanical analysis (d.m.a).: the α relaxation at −60°C and the β relaxation at −125°C.
The molecular dynamics of the glass relaxation process of the blend (α-relaxation process) appeared at a lower temperature range compared with that of the pure PC.
Despite the importance of Poisson's ratio in materials science and engineering, its connection to molecular dynamics and relaxation processes in glass-forming systems remains unclear.
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