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With the improved chain mobility, molecular ordering was slightly improved, showing a bundle-like ordering without regular packing.
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At 10 μM peptide, marked reversible changes in molecular ordering were observed for all membranes except DMPE/DMPG.
Understanding molecular ordering is a critical step in achieving molecular self-assembly for the fabrication of nanomaterials, and molecular ordering in the adsorption of large molecules on atomically flat surfaces can be characterized with precision by scanning tunneling microscopy (STM).
It is indicated that only when molecular chains in the amorphous phase approach their finite extensibility beyond a critical strain of about 1, accompanied by remarkable conformational ordering, can cohesive mesophase with certain molecular ordering be brought out to trigger strain-induced crystallization.
Interfacial molecular order is, therefore, strongly correlated with stoichiometry of the passive oxide film.
The manipulation and precise control of molecular order is a challenging prospect in the design and realization of devices for photonic applications.
As a result, fibre-like structures with well-defined molecular order are formed.
The resulting three-dimensional architectures with supra-molecular order are governed by the effective molecular geometries of the participating lipid building blocks.
Though the used P3HT had relatively high molecular weight, lamellar ordering was not entirely suppressed, as indicated by an arising Bragg-peak at q z = 0.38 Å–1, seen more or less distinct in all films of Figure 2. The fits for pristine as-made floated bilayers indeed indicate a sharp interface, with the determined interface roughness between P3HT and F8BT found negligible with σ RMS ≈ 0 nm.
The differences in the incipient molecular ordering, which are detected by SAXS but not by WAXS, could be responsible for the hardening observed in the glassy PET samples.
The morphology and molecular ordering have been studied by scanning and transmission electron microscopy, polarizing optical microscopy and wide-angle X-ray scattering.
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