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Similarly, mass spectra displayed the molecular ions corresponding to the respective molecular formulas of prepared compounds.
Collectively, from these measurements, molecular ions corresponding to pPtdEtn and aPtdEtn were definitively identified (Table 2).
Therefore, all molecular ions corresponding to PtdEtn were determined and tabulated (Table 2).
If a QqQ mass spectrometer instead of a high mass accuracy/high resolution instrument was used to analyze the molecular ions corresponding to PtdEtn molecular species in general and to pPtdEtn molecular species in particular, three approaches were employed.
Next, we profiled the diluted lipid extracts by using precursor-ion scanning of 196 Th (i.e., phosphoethanolamine) to further confirm the molecular ions corresponding to the pPtdEtn molecular species since these ions were enhanced (Figure 6C) due to differential fragmentation pathways as previously described [24].
LC/MS analysis of extracts of PbTx-2 exposure revealed molecular ions corresponding to products between brevetoxin and cytidine.
Similar(49)
Also notable is the appearance of a molecular ion corresponding to the mass of a didesmethyl-6-dEB analogue at the highest DSZS AT concentrations, suggesting competitive incorporation of a malonyl extender unit in other modules of the engineered DEBS assembly line harboring wild-type AT domains.
The 298.0969 molecular ion corresponds to MTA.
This series displayed, in their EI-MS spectra, molecular ions peaks corresponding to the mass of each formula and their elemental analyses agreed as well.
As a result, there were no molecular ion peaks corresponding to both biotin-PEG-NHS ester and RGD2 detected on MALDI-TOF mass spectrometry, except for the molecular ion peak of biotin-PEG-RGD2.
Specifically, we observed a molecular ion peak corresponding to a plasmalogen molecular species in which a low abundance fatty acyl carboxylate fragment A co-exists with an abundant fatty acyl carboxylate fragment B at the identical m/z during precursor ion scanning or product ion analysis.
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