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When the molecular cross section of the polar head group ((A)) decreases, the surface excess ((varGamma)) value increases for all the nonionic surfactants.
It is also found from Table 1 that as (varGamma) values increase the values of the molecular cross section of the polar head group ((A)) of the nonionic surfactants decrease accordingly.
Here, we describe the design and synthesis of a novel dendritic nickel porphyrin, NiTCPPA (meso-tetrakis- phenyl-4′-{ditert-butyl-4-caboxamido-4- 3-tert-butoxy-3-oxopropyl)heptanedioate}porphyrin) nickel (II)) that has a larger meso-tetrakis- phenyl-4′-{ditert-butyl-4-caboxamido-4- 3-tert-butoxy-3-oxopropylally occurring peripheral deposition profile of nickel.
MGBDs have cationic charges, narrow molecular cross section, and concave shape, allowing them to fit into the narrow minor groove of DNA [ 1].
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Molecular cross sections are calculated by means of a single-scattering independent-atom approximation in which the electron density of a bound atom is approximated by that of the free neutral atom.
Comparison between the dehydration of different alcohols reveals that a better separation performance could be obtained for alcohols having a larger molecular cross-section.
Microporous solids with pore diameters comparable to effective molecular cross-sections are mainly used as both stereo-selective absorbents and shape-selective catalysts.
For wavelengths above 200 nm, the molecular absorption cross section and the quantum yield are calculated by the model, while below 200 nm, their values are pre-defined.
The total photolytic rate constants are calculated by the model by integrating the product of the wavelength dependent exo-atmospheric flux, the atmospheric transmission function, the molecular absorption cross section and the quantum yield for each absorbing species.
Gas-phase ion size and shape are described by the molecular collision cross section (CCS), which can be calculated directly using the elution time from an electrostatic drift tube (typically on the order of milliseconds).
In this work, we describe computational techniques to predict the free molecular collision cross sections for fixed structural models of gas phase entities where inelastic and non-specular gas molecule reemission rules can be invoked, and the long range ion-induced dipole (polarization) potential between gas molecules and a charged entity can be considered.
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