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Conductance histograms display well-defined peaks denoting the most probable molecular conductance value at 4.2 × 10 4 and 1.7 × 10 5 G0 for Ni(nor) and Ni porph), respectively.
However, this value is smaller than the single molecular conductance value of 1,4-butanediamine with amine as the anchoring group, which may stem from weak interaction between iodine and Au electrode [31].
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The peaks at 4.2 × 10−4 and 1.7 × 10−5 G0 denote the most probable molecular conductance values of Ni(nor) and Ni porph), respectively.
Mechanically controllable break junction experiments and DFT calculations performed in this work suggest that the functionalization through the insertion of cyano (C≡N) in the basic perylene-diimide aromatic core is able to determine a preferential charge transport molecular path exhibiting a high conductance value comprised between 10−2 e 10−3 G0.
All the six metal complexes have been fully characterized with the help of elemental analyses, molecular weights, molar conductance values, magnetic moments and spectroscopic data.
All the metal complexes have been fully characterized with the help of elemental analyses, molecular weights, molar conductance values, magnetic moments and spectroscopic data.
Logarithmically binned histograms show an increase in the molecular conductance of Ni(nor) as E takes more negative values in the reduction direction and display well-defined peaks shifting from 6.9 × 10−4 G0 at E=−0.30 V to 1.3 × 10 4 G0 at E=+0.45 V (Fig. 5a and Supplementary Fig. 21).
Plateau at a conductance value of 10−3.6 G0 (19.47 ns) is also found besides the 1 G0, owing to the formation of molecular junction.
Inset: representative examples of STM-BJ conductracesdistance traces of Ni(nor) and Ni porph) featuring molecular conductance plateaus.
Estimation of the conductance value was performed.
Skin conductance value will be stored as hundreds of microsiemens.
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