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We could prepare molecular cavities with different sizes and shapes.
This resulted in molecular cavities complementary to the template in the imprinted polymer texture.
It can be attributed to the existence of two guests in the different molecular cavities with the different microenvironments.
By means of molecular imprinting of a conducting polymer, molecular cavities selective for oxytocin nonapeptide, an autism biomarker, were designed.
Imprinted films were characterized electrochemically using cyclic voltammetry (CV) and the encapsulated molecules were extracted from the films and complementary molecular cavities are formed that enable their rebind.
Some apparent scatter in the data might, in part, be associated with differences in the interactions of ortho-positronium with molecular cavities as polymer structures are varied.
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The diffusion behavior and solubility of gases in the molecular cavity were also simulated.
The calculations with ethanol as entrainer indicate that the molecular cavity and contact interaction are changed so as to increase the solubilities.
As shown in the examples reported here, the molecular cavity itself can be involved as a recognition unit for inclusion of the substrate or of part structures of the substrate.
The smart membrane contains subnano scaled molecular cavity which is constructed by polymer architecture, which is similar to the structure of small molecules separated and is aligned regularly in crystalline polymers.
The extremely high solubility of a larger gas and the controllable diffusion path in the narrow channels proved the applicability of the concept of the molecular cavity to high performance separation membranes.
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CEO of Professional Science Editing for Scientists @ prosciediting.com