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Deformation behavior of several polyethylenes and ethylene-based copolymers with various molecular architecture (linear and branched polyethylene, ethylene based copolymers), and a broad range of molecular mass and its distribution, was studied.
The obtained results indicate that the molecular architecture (linear or branched) and the number of hydroxyl groups per unit mass of PDLLA alter the hydrolytic degradation mechanism, behavior, and rate.
This paper reports the effects of hard (polystyrene, PS) and soft (polyisobutylene, PIB) segment composition and the molecular architecture (linear versus star, PS and PIB block length) on the morphology and mechanical properties of polystyrene/polyisobutylene (SIBS) block copolymers synthesized by living carbocationic polymerization.
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The change of molecular architecture from linear to 3-arm star type resulted in an improved phase separation at lower PS content and better thermoplastic elastomer properties.
Various operating conditions, such as the polymer concentration, the amount of non-solvent and the characteristics of the raw polymer (molecular weight and architecture: linear vs. branched) have been investigated.
These systems are characterized by a much larger set of parameters, not only in terms of composition and interaction parameters but also in relation to the molecular architecture, for example, linear versus star.
CHS-Phe with linear molecular architecture displays higher removal efficiencies of antibiotics than commercial flocculants.
The two molecular chromophores differ by their architecture, linear (M1) vs propeller-like (M2).
By selecting the fatty acid distribution function of plant oils via computer simulation and the molecular connectivity, chemical functionalization and molecular architecture can be controlled to produce linear, branched, or cross-linked polymers.
The molecular dynamics of two polyurethanes with different architecture (linear and hyperbranched) and their blends with compositions 80/20 and 65/35 have been studied by dielectric spectroscopy and dynamic mechanical analysis yielding results complementary to those obtained by differential scanning calorimetry.
The relationships between the molecular architecture and the precursor composition were compared to that of a linear poly(dimethylsiloxane) precursor.
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