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This led to the identification of 8 improved mutants, among which mutant I285R showed nearly 3-fold increase in catalytic efficiency for the ε-caprolactone opening, first step of the reaction, and 30% increased poly(ε-caprolactone) molar mass compared to parental wild-type CalB enzyme in same reaction conditions.
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At pH 2.7, the marked change in the molar mass as compared to 0.1 and 0.5 M K2SO4 supporting electrolytes was rationalized by assuming that hydrated proton transfer takes place.
We incubated PtAu1aLOV together with PtAu1abZIP upon which the elution volume shifted to a lower volume and the molar mass signal increased slightly compared with PtAu1aLOV alone.
Hydrogenated polymers of P7 and P14 (PH7 and PH14, respectively) exhibited a large decrease in apparent molar mass and much broader dispersity compared to the unsaturated precursors.
The preliminary results demonstrated that a needle-like shaped clay promotes higher molar mass and better mechanical properties compared with laminar clay.
This can be attributed to the much slower diffusion and exchange rates of amphiphilic block copolymers compared to molar mass surfactants [ 1].
Compared with low molar mass surfactant micelles, polymeric micelles are generally more stable, exhibiting a remarkably lower CAC [22].
A conventional epoxy system and a low molar mass difunctional acrylate are studied and compared.
The resulting molar mass distributions for different sets of polyamides were compared with molar masses that were determined directly by SEC MALLS and excellent correlation was obtained.
The polymer number average molar mass (Mn) determined by size exclusion chromatography (SEC) compared with polystyrene standards and the corresponding theoretical value were only in good agreement for the polymers containing aryl groups.
For the determination of PK parameters of carboplatin, the measured platinum concentrations were multiplied by the molar mass ratio 1.903 (carboplatin : platinum) in order to compare them with the results of other authors.
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