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In high humidity, however, it is difficult for a-ZnO NBs to segregate from the moisture solution, which means that the Zn2+ ion concentration in moisture solution is not high enough to meet the condition of saturation forming a-ZnO NBs.
Due to the interaction between the surface of c-ZnO NWs and moisture solution, the radial concentration of Zn2+ ion would be changed because Zn2+ ions gradually dissolve and diffuse from the original c-ZnO NWs surface into the moisture solution.
When the concentration of Zn2+ ion in moisture solution meets the saturation condition, the Zn2+ ions start to segregate out from the moisture solution; the a-ZnO NBs cause to grow from the main body of the original c-ZnO NWs, which can be seen in Figure 2b.
When the Zn2+ ions and the ZnO NBs start to segregate out from the moisture solution and cause to grow from the main body of the original ZnO NWs, respectively (inset).
The c-ZnO NWs surface passivation can slow down the interaction between the moisture solution and c-ZnO NWs surface; the passive c-ZnO NWs would not have the spontaneous reaction in the same humidity treatment, as seen in Figure 4a,b,c,d).
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