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The bromide ligands have migrated to the Lewis acidic Hg CN 2 moiety with concomitant transfer of the cyanide groups to the cobalt III) centre.
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In the case of Bchl-ser, however, a phototoxic effect has also been seen under hypoxic conditions (pO2 ≈2.5 mmHg) (Chen et al, 1998) and a model has been proposed in which the excitation of a Bchl-ser molecule coordinated with an oxygen molecule prior to illumination leads to dehydrogenation of the Bchl moiety, with the concomitant generation of hydroxyl radicals (Katz et al, 1998).
The F/V-type ATPases couple transfer of protons or sodium cations across their membrane moieties with the concomitant hydrolysis or synthesis of ATP via a binding-change mechanism in their protruding catalytic parts [ 1, 3, 9, 13].
In a similar manner, an alkoxido group could be transferred to the R′C(O) moiety of the anhydride with concomitant formation of an ester (Scheme 1; X = R′CO).
The recognition takes place through the Hoogsteen binding site of adenine with concomitant PET quenching of the anthracene moiety.
The anion recognition takes place through charge neutral thiourea receptor sites with concomitant fluorescence quenching of the coumarin moiety with 1 showing a strong binding to C6H5COO− over F− with a distinct change in color.
Carboxylic acid binding takes place through charge neutral pyridyl amide receptor sites with concomitant quenching of fluorescence of the triphenylamine moiety.
Ion-spray mass analysis of the inhibited E. coli GGT confirmed the formation of a 1 1 covalent adduct with the catalytic subunit (small subunit) with concomitant loss of phenoxide, leaving the peptidyl moiety that presumably occupies the Cys-Gly binding site.
Subsequently, a proteinyl enzyme thioester intermediate is formed with concomitant release of the C-terminal target protein moiety.
When the LB-architecture on gold substrate was contacted with a solution of 3-penthylthiophene electropolymerization of the latter could be achieved and islands of the poly 3-penthylthiophene) were observed with concomitant disapoly 3-penthylthiophenenal of the grafted TT moieties.
Hydride transfer from C-4 of the nicotinamide ring of NADPH to the Si-face of the carbonyl with concomitant protonation of the resulting hydroxyl group by the catalytic acid Tyr152 then generates the (R -Lac moiety of epilancin 15X and NADP+.
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