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Polymers containing guaiacol moiety were obtained via conventional radical polymerization of this monomer with AIBN as initiator.
A group of related regioisomers possessing either a p-aminosulfonylphenyl (16) or a p-azidosulfonylphenyl (17), moiety were obtained by chlorosulfonation of the unsubstituted 3,4-diphenylfuroxan (10) and subsequent reaction with either ammonium hydroxide or sodium azide, respectively.
A novel series of sulfonamide derivatives 4 21 have been synthesized starting from the strategic starting material (E -4-Chloro-N- 4- 1- 2- 2-cyanoacetyl)hydrazono)E -4-Chloro-N- 4- 1- 2- 2-cyanoacetylwo sE -4-Chloro-N- 4- 1- 2- 2-cyanoacetyl10–21 dE -4-Chloro-N- 4- 1- 2- 2-cyanoacetylty wE -4-Chloro-N- 4- 1- 2- 2-cyanoacetyl
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The NCN-pincer platinum II) complex bearing the furanopyrimidine moiety was obtained by the reaction of the NCN-pincer ligand bearing the furanopyrimidine moiety with [Pt tolyl-4 2 SEt2)]2.
To synthesize the tricyclic pyridoquinazolinones, new pathways were designed: the angular moiety was obtained starting from 6-aminoquinazolinone to form the pyridine ring and the linear one starting from the 6-aminoquinolinone to form the pyrimidine ring.
An additional product containing the oxazoline ring in daunosamine moiety was obtained during the synthesis of formamidinodoxorubicin from DOX. Formamidine derivatives demonstrate better anticancer properties when compared with parental DOX, such as lower cardiotoxicity and comparable or higher antiproliferative activity.
O-phthaldialdehyde reagent (OPA) containing OPA (1 mg ml-1) with 2-mercaptoethanol as a sulfhydryl moiety was obtained from Sigma.
Through aminolysis of the xanthate and thioacetate moieties, copolymers with free thiol moieties were obtained.
Thus, water soluble polyelectrolytes decorated with high amounts of photochemically active moieties were obtained.
Two amines containing biphenyl moieties were obtained for the first time.
Polymers having (E)- and (Z -olefin moieties were obtained, wherein the (E)-/(Z -olefin depended on the reaction conditions.
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