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Base on the absorption spectra, fluorescence spectra, ESI-MS and 1H NMR spectra analysis, the fluorescence response was attributed to Cu2+-promoted hydrolysis of the picolinate moiety to yield a highly fluorescent product, 6-acetyl-2-hydroxynaphthalene (1).
In the presence of a quaternary ammonium or phosphonium bromide as an initiator, monomer 5 undergoes an AB polymerization via nucleophilic ring-opening of the epoxide group with the carboxylic acid moiety to yield high-polymeric hydroxy-functionalized aliphatic polyester (6).
Upon induction of autophagy, a cytosolic protein, microtubule-associated protein 1 light chain 3 (LC3is is processed and covalently linked to a phosphatidylethanolamine moiety to yield LC3II.
As precursors for phenylpropene production, the monolignol alcohols undergo first acetylation of the C9 hydroxyl group [3] and then reductive cleavage of the acetate moiety to yield the propenyl side group [4], [5].
Once in the cell, normal metabolism cleaves the fatty acid moiety to yield the active drug.
Specifically, the hydroxyl radical can abstract a hydrogen atom from the 2-deoxyribose moiety to yield carbon-centered radicals.
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Nudix hydrolases hydrolyze substrates of general structure nucleoside diphosphate linked to another moiety, X to yield nucleotide monophosphate and P-X [ 33].
Upon UV irradiation, the APB moiety decomposes to yield a nitrene that covalently inserts itself at two specific DNA sites, hence suggesting a defined arrangement for the H2A N-terminal tail with respect to nucleosomal DNA.
In a third step, stachyose synthase (SS, EC 2.4.1.67) transfers the galactosyl moiety from Gol to the C6 position of the Gal moiety in Raf to yield the tetrasaccharide stachyose (Sta, Suc-Gal2).
The signaling is due to the oxidative desulfurization of the thiocarbonyl moiety by HOCl to yield oxocarbonyl function.
In this in situ hydrogenolysis reaction system, it was elucidated that both hydrogen production from methanol and selective hydrogenolysis of the furan moiety proceeded simultaneously to yield monophenolic compounds and gaseous hydrogen.
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