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A (R,R -2,5-dimethylphospholane moiety is also included.
An interpretation of the experimental findings, related to the behaviour of previously reported polymeric photoinitiators based on the benzoin methyl ether moiety, is also reported.
Resulting from this study, a structurally novel class of submicromolar fibrinogen GPIIb/IIIa binding inhibitor bearing 1,2,4-oxadiazol-5 1,2,4-oxadiazol-5 1,2,4-oxadiazol-5
Akin to the synthetic antioxidants, butylated hydroxytoluene (BHT) and butylated hydroxyanisole (BHA), the electroactive di-tert-butylphenol moiety is also present in the darbufelone structure thus conferring reducing properties.
The first one-electron stage ranging from − 1.1 to − 1.9 V leads to free-radical species in which the density of the unpaired electron is located predominantly at the indandione moiety (radicals of the semidione type) although the pyridinium moiety is also involved.
O(11) – H(11) group of cation moiety is linked through hydrogen bonding to O 8) of the carbonyl group of anion and O(10) – H(10) of cation moiety is also linked through hydrogen bonding to O 9) of the carbonyl group of anion.
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A side reaction of the unsaturated moiety was also shown.
A reference compound without carbazole moiety was also prepared.
Moreover, N-[2- piperazin-1-yl)ethyl] moiety was also ideN-[2- piperazin-1-ylally alterN-[2- piperazin-1-yluN-[2- piperazin-1-ylw directioN-[2- piperazin-1-yludiethyl
The coordination ability of these species towards the W CO 5 moiety was also investigated; calculations indicate a predilection for the coordination through the germanium atom.
The crystal structure and spectral properties of its congener 4b that contains one 12-bromo [2.2]paracyclophane group and rhodamine moiety are also investigated for a comparison.
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