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The latter measurements are essential for amorphous materials: their comparatively mobile segments cross polarize inefficiently and are thus undercounted in the traditional CPMAS spectrum, whereas their most rigid molecular moieties will display broadened resonances if the H decoupling field is too small.
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In general, the rank(N ε') = m0 < m and the system defined above will display moiety conservations - certain metabolites can be expressed as linear combinations of other metabolites in the system.
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