Aniline moieties are coordinated to carborane icosahedra by CB bond formation, whereas NB and possibly CB bonding was observed for pyridine/metacarborane films.
The second half of the salicylaldimine moieties was coordinated to Zn2+.
In the previously reported other similar complexes, the fluorenyl moiety is coordinated with the metal center in an η 5-coordination mode, but it is coordinated in an η 1-coordination in the present examples [102].
1H-NMR indicated that phenyl ring of borate moiety is coordinated with Zr-metal center, and these complexes have similar structures both in solid (confirmed by crystal structure) as well as liquid phase.
The adenosine ring of AMPcPP packs into a cleft formed by Leu76, Lys80, Ile104, Leu117, Thr118 and His121, and the triphosphate moiety is coordinated by the two Mg2+ ions bridged between two absolutely conserved aspartate residues, Asp101 and Asp103.
In particular, it shows how the γ-phosphoryl moiety is coordinated in the active site in the closed state.
The characterization results showed that the two platinum II) moieties, [cis-Pt(NH3 2]2+, [Pt(bpy)]2+, and [Pt phen)]2+, were coordinated to the mono-vacant site of [XW11O39](12−n)− (Xn+ = Al3+, B3+, and Ge4+) and [α2-P2W17O61]10−.
The ionized sulfonamide moiety of valdecoxib is coordinated to the catalytic Zn II) ion with a tetrahedral geometry.
In this imprinting, protonated primary amine groups of the templates were complexed by the benzo-18-crown-6 moiety of 24, the diol groups of DA formed hydrogen bonds with the 3,4-dihydroxyphenyl substituent of 25, and the imine nitrogen atom of the imidazole or purine moiety of histamine and adenine, respectively, was coordinated by the boron atom of the dioxaborinane substituent of 26.
The ligand Hintsc contains the thiosemicarbazide (TSC) moiety through which Ni2+, Mn2+ and Fe3+ metals are coordinated.
