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Surprisingly, the addition of monomeric complementary moieties resulted in an even greater rate enhancement.
Those monomers with more benzoxazine moieties resulted in higher polymerization rate.
An increase in polar moieties resulted in enhanced permeability and selectivity with respect to the pure polymer.
Four of its peripheral galactopyranosyl moieties resulted in improved water solubility confirmed by a 1-octanol/water partition coefficient log P value.
Tetrahydro-β-carboline analogues showed moderate activity whereas the presence of p-trifluoromethylbenzoyl and p-toluenesulphonyl moieties resulted in complete suppression of antischistosomal activity.
The high substrate tolerance of these enzymes towards different FA and alcohol moieties resulted in the biosynthesis of a broad range of MBE.
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Four-arm star thymine-telechelic PIB was obtained as a tough rubbery material as proven via melt-rheology and SAXS measurements with clusters of ≈10 hydrogen bonding moieties resulting in a self-healing response at room temperature.
1-Position substituted analogue exhibited a large twist angle of 52.0° and a strong electronic coupling between the core and the peripheral moieties, resulting in the strong dipolar property and the high fluorescent quantum efficiency of over 80% in the solution and the solid state.
A thin film of flower-like alumina – obtained by sol gel – was deposited and combined with fluoroalkylsilane moieties, resulting in a hybrid coating with excellent repellence to water (static contact angle of 179 ± 1°) and self-cleaning properties (contact angle hysteresis of 5 ± 1°).
Lead structure 1 was also linked to a 4-aminobutanoic acid 2. HBED-CC was conjugated to the aforementioned pharmacophores (1 and 2) via its functionalized propionic acid moieties, resulting in monomers 3 and 4 or dimers 5 and 6, respectively.
Perhaps related to their anti-predatory properties in marine systems, the cytotoxic nature of cyclopentenone prostaglandins occurs, in part, due to the reactive α,β-unsaturated carbonyl group in the cyclopentenone ring, which can undergo nucleophilic addition with electrophilic moieties, resulting in protein and DNA adduct formation [36] [39].
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