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Proteinaceous moieties might be physically encapsulated within the aliphatic moieties of humic acids [44].
Polar and apolar moieties of humic acids are spatially separated forming domains of different polarity.
Here we report how isotope-filtered nD NMR enables characterization of phenolic moieties of humic molecules and illustrate its principles using a 4D CH3O-filtered NMR experiment, 4D HCCH3, which correlates chemical shifts of four nuclei the aromatic CH atoms ortho to methoxy groups and those of CH3O atoms.
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We illustrate this approach by identifying major substitution patterns of phenolic aromatic moieties of a peat soil fulvic acid, an operational fraction of humic substances.
Photodegradation of humic substances causes drastic changes in the UV vis absorption and fluorescence properties of humic acids.
CP/MAS 13C NMR spectra of humic acids.
The recalcitrance of proteins in humic substances was achieved by encapsulation into hydrophobic domains of humic substances.
Hypothetically, the absorbance increases with the concentration of humic substances.
Magnetite coated with Aldrich humic acid (HA) and Elliott Soil humic acid (HAES), respectively, were prepared, and the two kinds of humic acid influenced the ability of Mt to promote syntrophic metabolism of the co-cultures in a similar way.
The numbers of pepper flowers and fruits increased significantly in response to treatment with humic acid, IAA and a combination of humic acid and IAA.
Our results with CaCl2 indicate that in the presence of humic acid, FNP aggregates have a more open and loose structure than in the absence of humic acid.
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