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The novel (S -BINOL-based S -BINOL-basedporating triazole moietieS -BINOL-basedained by click reaction.
The relative amount of the two types of carbonate moieties could be controlled by addition of the appropriate catalyst.
A series of main-chain polyurethanes containing sulfonyl-based NLO chromophores in the polymer backbone were prepared, the subtle structure of the chromophore moieties could be easily modified to adjust the property of the resultant polymers.
In this design, the high loading capacity and wrapping of the CS-DAT and III organic moieties could be achieved, leading to the formation of silica core with multi-shells that formed from double-silica, CS-DAT, and III dressing layers.
Hybrids of both moieties could be further developed to explore their biological activity as anticancer.
The location of the methyl groups and the olefinic moieties could be assigned on the basis of COSY, HMBC, and NOESY correlations.
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Our findings indicate that the α,β-unsaturated moiety could be a pharmacophore for TJ opening.
Notably, modified opioid peptides bearing alkynyl moiety could be further functionalized through well-established click reaction.
The hexadecanol moiety could be suggested as a positive modulator for the enhancement of CO2 hydration.
As the residues involved in the benzamidine binding are widely conserved among GPCRs, the unprecedented inverse-agonist mechanism by the benzamidine moiety could be adapted to other GPCRs.
These results indicated that hydrazone derivatives containing pyridine amide moiety could be developed as novel and promising insecticides.
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