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The perfluoroalkyl moieties are in the shell layer and the fluorine contents in the whole system range from 0 to 12.83 wt%.
In this chain adjacent adenine moieties are in different planes and forming a N-H…N base pair with two different chain adenine moieties, but alternate adenine moieties; are in same plane and form a base pair with the same chain adenine moieties (Figure 7a). Figure 7 The formation of N-H…N N-H…Npair.
Additional substituent modes, such as 1, 3-di-, 1, 3, 4-tri-, 1, 3, 4, 6-tetra-galloyl groups and 4, 6-HHDP moieties are in existence as well.
Furthermore, the absence of a peak assigned to –COOH units in the spectrum of the precursor salt, Ag/ACD, indicates that all acetylenedicarboxylic moieties are in anionic form coordinated with silver cations.
The data of the glycoside moieties are in agreement with those published by Lu et al. [ 18] and were established as 3- O- α-L-rhamnopyranosyl(1 2)- α-L-arabinopyranoside and 28- O- α-L-rhamnopyronosyl(1 4)- ß-D-glucopyranosyl(1 4)- ß-D-glucopyranosyde.
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The conversion of bisimide moieties was in the range 60 100% depending on polymer chain flexibility.
In agreement with our model, the replacement of the quinoline moiety by bicyclic or tricyclic moieties was in general detrimental on the inhibition activity compared with the monocyclic substitution (14– 18; Figure 2).
In contrast, when the carboxylate moiety is in ortho, ligands like diclofenac or meclofenamic acid bind in a different orientation.
When the carboxylate moiety is in meta or para, the inhibitor binds in such a way that the carboxylate forms a salt bridge with Arg120.
When this moiety is in the meta- or para- position, these interactions with HBP3 appear to be lost, resulting in a loss of activity (cf. compounds 10 and 14 of Table 1).
The M1dG moiety is in the ring-closed form and base-stacked between adjacent template bases.
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