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A cyclic dimer consisting of two [2]catenane moieties and two biphenylene units was formed along with the polymer.
Complex 1 consists of a discrete centrosymmetric mononuclear unit, in which cadmium II) is octahedrally coordinated by two pyrazene and two tetrazolate nitrogen atoms of two PZTZ− moieties and two oxygen atoms of two water molecules.
A new series of short axially symmetrically (4a and 4b) and asymmetrically (4c and 4d) 1,3,6,8-tetrasubstituted 1,3,6,8-tetrasubstitutedith two phenyl moieties and two diphenylamine units on the pyrene compounds designed and synthesized based on stepwith syntwotic strategy.
Each Co II) ion forms two dative bonds with the nitrogen atoms of two deprotonated imidazole moieties and two ionic bonds with the nitrogen atoms of two other imidazoles (Fig. 1).
PARP proteins are composed of two ribose moieties and two phosphates per unit polymer.
One singlet at δ = 2.18 ppm was assigned to the CH3 groups of the xylyl moieties and two singlets at δ = 1.95 and 1.98 ppm to the two acetate ligands.
Similar(54)
The physicochemical properties of about 100 polyesterdiols were measured, the polyol molecular structure being built on three diacidic moieties and three glycolic moieties in various proportions.
In the present study, we designed a small library of 38 novel compounds containing a heteroaryl-phenyl scaffold possessing several (bioisosteric) moieties, and twelve new precursors.
The MALDI-TOF MS analysis shows that each repeating unit of polymer chain consists of one unit derived from the tetrafunctional moiety and two bisphenoxy moieties exhibiting ladder structure in the polymer backbone.
H-Phe-Ser-OH was selected as a pro-moiety, and two prodrugs were synthesized, i.e. H-Phe-Ser(Ibuprofyl -OH and H-Phe-Ser(Bz)-OH.
X-ray single crystal structural analysis shows that the dihedral angles involving the difluorophenylene moiety and two pyridine rings of the 2,2′-bipyridine unit in (2Fphen-bpy)Eu DBM 3 are 42° and 51.6°, indicant of non-conjugation between the two segments.
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