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The WO3 film annealed at 100 °C shows the fastest color-bleach kinetics, highest optical modulation and coloration efficiency, which is a repercussion of the pentagonal channels equipped with the tetragonal phase, the mesopore structure and the channeled porosity.
Prototype ECDs fabricated using these SPEs rendered excellent optical modulation and coloration reversibility.
An optimum crystallite size and high ion storage capacity in the 300 °C annealed film has led to its superior electrochromic activity with the transmission modulation and coloration efficiency of the same film being 42% and 8.1 cm2 C−1, respectively at 550 nm.
A comparative study of spin and dip coated nanostructured thin films (annealed at 250 °C) revealed a superior performance for the cycled dip coated film in terms of higher transmission modulation and coloration efficiency in solar and photopic regions, faster switching speed, higher electrochemical activity as well as charge storage capacity.
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It was found that composite electrode shows enhancement in electrochromic properties in terms of optical modulation (ΔOD) and coloration efficiency.
Compared with the typical five-layer ECD-1 (ItheNiOx/LiNbO3/WO3/ITO), the seven-layer ECD-2 with the structure of ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO presents much less leakage current, larger optical modulation and higher coloration efficiency during electrochemical cycling.
Due to its highly porous plate-like morphology, the 400 °C-annealed WO3 film has the highest optical modulation of 52% and coloration efficiency of 71 cm2/C at 633 nm.
The dry-lithiated nano-crystalline films demonstrated better optical modulation of 36.1% and coloration efficiency of 26.2 cm2/C at a wavelength of 550 nm.
Lin et al.[30] reported an optical modulation of 36.5% and coloration efficiency of 33.7 cm2/C at a wavelength of 400 nm for reactively sputtered thin films of V2O5 − z at a room temperature of 23°C on flexible PET/ITO substrates.
Coloration/bleaching switching time is expressed as the time needed to reach 90% of its maximum modulation during coloration and bleaching processes.
Enhancement in electrochromic properties in terms of optical modulation (ΔOD), coloration efficiency (CE) and switching times (tb and tc) was studied and reported.
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