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spectra of the modified polymer displayed the characteristic features of slow exchange between the free and the aggregated states for the alkyl chains.
Finally, the polymers were evaluated as the donor materials for polymer solar cells, which all presented high open-circuit voltage around 1.0 V, and the branched 3,7-dimethyloctane modified polymer displayed the best performance with a PCE of 2.66% (Voc = 1.01 V, Jsc = 6.71 mandm2 and FF = 0.39).
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Their properties were compared with those of the parent polymers derived from 1,3-phenylenediamine. The modified polymers displayed better solubility than the unmodified ones and dissolved in polar aprotic solvents and certain inorganic and organic acids.
The modified polymer is an even more effective carrier.
Use of modified polymers is practically boundless.
These modified polymers were then characterized by H-NMR.
These modified polymers also showed tendency to self-assemble to form nanostructures.
The modified polymers could then conjugate to GST and a GST fusion protein through photoactivation.
To demonstrate the ability of the modified polymers to bind pDNA, gel retardation assay was done.
After deprotection and sulfation, the heparin-mimicking polymer displayed delayed clot formation and reduced complement activation.
Oligomers and polymers displayed high thermal stability.
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