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The CV response recorded at Au/S-Calix modified electrode revealed an unusual time evolution of the surface coverage.
The results obtained from methanol oxidation over the graphene hybridized MoNiCoS modified electrode revealed suitable electrocatalytic properties and a considerable diffusion current, confirmed by the Tafel plots through calculating the exchange current (io) as an important kinetic parameter of electron transfer.
Electrochemical behaviors of K3[Fe CN 6] on the modified electrode revealed that activated silica gel was capable of facilitating electron transfer and increasing surface area.
The designed modified electrode revealed linear responses in the ranges of 0.5 nM–10 nM and 0.08 μM–2 μM with a limit of detection of 0.1 nM (S / N = 3).
Differential pulse voltammetry (DPV) measurement at β-CDP/rGO/GCE modified electrode revealed that the reduction peak current increased linearly with the concentration of IDP in linear range of 5 × 10−8 to 1.5 × 10−5 mol L−1 and 2 × 10−5 to 1.5 × 10−4 mol L−1 with detection limit of 2 × 10−8 mol L−1 at a signal-to-noise ratio of 3.
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Detailed EIS analysis of different modified electrodes revealed that the charge and mass transfer processes were accelerated at the modified electrode electrolyte interface, which could be ascribed to the large specific surface area, the surface defects and the oxygen functional groups of the SWCNT.
The electrochemical measurements reveal the modified electrode possesses the excellent antifouling capability for DA oxidation and long-termed stability.
Cyclic voltammetry studies revealed that the modified electrode can increase the reduction current of H2O2.
The results revealed that the modified electrode shows an improvement in anodic oxidation activity of CA due to a marked enhancement in the current response compared with the bare carbon paste electrode.
Hydrodynamic voltammetry revealed that the modified electrode was catalyzed effectively by the four-electron transferred reduction of dioxygen into H2O with minimal generation of H2O2.
The results revealed that the modified electrode could enhance electron transfer of Cyt c and retain electrochemical activity, good stability and reproducibility.
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