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Incorporation of a small quantity of linear LDPE having a relatively narrow molecular weight distribution to the conventional LDPE having a long chain branched structure and broader molecular weight distribution lessens the shear thinning behaviour of the modified blends of the two component polymers.
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Among all waste engine oil modified blends, addition of waste engine oil resulted in corresponding decrease in complex modulus values at all frequencies.
Surprisingly, mechanical characterization of modified blends revealed that the use of hollow plastic micro-spheres provides greater yield strength than that of similar blends with equivalent rubber content.
The systematical study on the structure property relationship revealed that the thermal and mechanical properties of modified blends strongly depend on inclusion size.
The mechanical performance of the modified blends is strikingly dependent not only on the interfacial activity of the copolymers but also on the mechanical properties of the copolymers, particularly at the high copolymer concentration.
Use of both polymers increased the viscosity of polymer modified blends marginally when compared to unmodified binder.
Morphology of unmodified blends showed coarse dispersion, whereas that of the modified blends showed fine and lamellar dispersion.
Based on the phase morphology, the ultimate tensile properties and the dynamic viscosity of the modified blends, the tapered diblock copolymer is clearly the most efficient emulsifier.
Complete lack of female response to hexane control further supported female recognition of the modified blends.
The modified blends show very high dielectric constant value (105 107) as a function of frequency (in the range 50 Hz–35 MHz) and temperature in the range (40 150 °C).
The rate of crystallization is highest in unmodified blends and lowest in neat polymers while intermediate in modified blends.
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