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The quadrupole modes were not observed on quartz [Fig. 5(b)] or film with a zero absorbance [Fig. 5(c)].
The harmonic modes were not stable and occasionally lasted for only 30 s.
However, in our samples, the vibrations were slightly shifted and some vibration modes were not detected.
The other apparent peaks might be due to metallic counterpart, since these modes were not reported with graphite-like materials.
The access trip was equally realized with a private (45%) or a public transport mode (46%); other transport modes were not much used.
A similar phenomenon has occurred before modeling phosphate adsorption onto goethite where higher-frequency peaks associated with P-OH vibrational modes were not detected in observed spectra.
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However, these modes are not observed in the experimental spectra.
The axisymmetric and other asymmetric modes are not studied.
However, the resonant modes are not so sensitive to the perturbations of c13, e31 and e33.
These modes are not easy to implement for SMEs and evolve over time.
Note that both the ZA and ZO modes are not Raman active at the Γ-point, where q = 0.
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