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Four 2,5-pyridine dicarboxylate (pydc) metal (Mn, Mn/K, Zn, and Nd) coordination polymers with 2D and 3D architectures were synthesized, in which pydc ligand exhibits four new coordination modes to link up to seven metal atoms.
Single-crystal X-ray analyses reveal that the 2,4′-diphenic acids acts as bridging ligands, exhibiting rich coordination modes to link metal ions: bis-monodentate, bidentate chelating, chelating/bridging, monoatomic bridging and monodentate modes.
While in 4, both of the two carboxylate groups of the pzda ligand adopt μ2-O bridging modes to link Mn II) ions into a 1D coordination polymer, which is further assembled into a 2D supramolecular network containing double-stranded hydrogen-bonded helical chains.
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Complexes 1 and 2 have 3D metal-organic frameworks containing a 1D tri-strand array, in which the pzda ligand adopts a pentadentate mode to link lanthanide ions.
Results show that adding links capable of using sleep mode to link aggregation groups is a more energy-efficient technique compared to using less links in link aggregation groups, even if they had more advanced energy-saving features like rate adaptation capabilities.
We have also implemented another mode to link specifically with Taverna where the input is not the collection reader but instead a list of String (depth 1) which is passed to the 'input_text' port of the U-Compare plugin.
Complex 1 consists of two types of ligand-binding modes contributing to link the PrO7N(H2O) polyhedral chains to three-dimensional (3D) open-framework architecture.
Furthermore, by allotting capacity with different mode to links, a manner of enhancing the performance of networks is introduced, which should be helpful in the design of traffic networks.
Roni Size made "New Forms," a drum-and-bass album that wasn't just for the dance floor; then, for "In the Mode," he decided to link the hurtling, jittery momentum of drum-and-bass to songs based in hip-hop and rhythm and blues.
Testable econometric modeling systems were built to link mode split and mode specific travel distances with local economic and urban form characteristics in four different population sizes and two urban form types, based on 187 travel surveys in 108 Chinese cities in the past two decades.
Common themes, tropes and modes of expression seem to link the authors of the outer chapters with Daode Jing.
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