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In other words, the heating causes the modes to blueshift.
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It was noticeable that the peaks of Raman E 2 (high) phonon mode were variable; it blueshifts at the interface of film/substrate, then goes to steadiness in the following, after that the peaks fall down and then returned to blueshift; the linewidth of the E 2 phonon was approximately 2.6 cm-1 near the surface and increased with decreasing distance from the interface of film/substrate.
At low GOx concentration, a low supply of H2O2 favours the deposition of a homogeneous silver coating on the Au nanostars, leading to blueshift of the LSPR band.
With decreasing film thickness, the A1g peak is redshifted, and concurrently, the E1 2g mode is blueshifted due to the weakened interlayer interaction, leading to a decrease in the frequency separation between the two modes.
The broad resonant of the U-shaped nanocavity is split into two resonant modes: one is blueshifted while the other is redshifted [12, 13]. Figure 3c e displays the electric field distributions of resonant modes at 2408, 2437, and 2457 nm respectively.
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