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14c Undeterred, acid chloride formation and Hunsdiecker reaction pleasingly gave the desired trans-configured chlorocyclopropane 47 in excellent diastereoselectivity (d.r.=97 3) in moderate yield over two steps.
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19a b However, these salts were synthesized in moderate yields over several steps and are therefore unattractive for application in standard arylation reactions.
The main advantage of this synthesis is the higher yield of ligand precursors and a moderate yield of complex 64.
In the case of cyclohexene oxide, a moderate yield of 56 % with 63 % selectivity was obtained.
Although 3 is obtained in poor crystalline yield or moderate yield in crude form, the synthesis is reproducible.
Both 18 and 19 were obtained as reported with moderate yields in two steps [22].
At 30°C, moderate yields of benzil were observed in all three solvents.
The three MoBio kits had moderate yields (0.7 4 μg).
Similarly, propargylic alcohol-tethered furans are converted into benzofuran derivatives in moderate yields.
This catalyst proceeded to give the enantiomeric bicylopropane product with moderate yields and enantioselectivity.
Purification was moderate, yielding a specific activity of 11.9 U/mg (56% yield).
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