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Silylborane 2b furnished 3b in moderate yield under otherwise optimized reaction conditions.
Moreover, the γ-substituted alcohol 1v afforded 2v in moderate yield.
As shown, steroid derivative 7 was synthesized in moderate yield (41%) under the same reaction conditions.
Synthesis of twelve new derivatives was accomplished with moderate yield (70 76%).
The polymerization proceeded well in homogeneous manner to give a moderate yield of polymer.
Moderate yield came from decomposition of V-Cz and self-coupling of triiodo-triphenylamine.
After screening the reaction conditions (Supplementary Tables 1 and 2), a moderate yield of 3a was obtained in the absence of an exogenous ligand (entry 1, Table 1).
Acetaldehyde azine (AcAz) underwent 'crisscross' addition with two equivalents of phenyl isocyanate to form a one-to-two adduct in a moderate yield (63.0%).
Control experiments have demonstrated that both the nickel catalyst and Mn dust are essential for the desired transformation to proceed, while moderate yield of 3 can be obtained in the absence of ligand, indicating the chelating ability of the pendant ester group (See Supplementary Table 1).
The catalytic carboxylation of the C sp3 -F bond of 4C sp3 -Fccessfully achieved in moderate yield bondhe sequential reactiof, i.e., via a Ni(COD)2-catalyzed defluorosilylation, followed by a C(sp3)-Si bond activation to incorporate CO2 under promotion of a fluoride anion (Fig. 3d)30.
In the case of cyclohexene oxide, a moderate yield of 56 % with 63 % selectivity was obtained.
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